Yes it can be done as long as your Excel database is set up correctly (i.e. no gaps in lists etc.).
Open Word, format the page layout as you want, select the 'Mailings' tab, click on 'Start Mail Merge' drop-down arrow and if you are uncertain as to what to do at this point then select the last option 'Step-by-Step Mail Merge Wizard' and then go for it!
Cheers,
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