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Default Mail Merge: start mailing from Outlook but they are sent from OutlookExpress

I am trying Mail Merge from Office-2000 using hints at
http://support.microsoft.com/kb/287561/en-us
It works but funny thing happens/ I start with Outlook, then it passes the
matter to Word
Word takes the addresses form Outlook
But then it passes the whole thing to Outlook Express.
Where and what do I set so that emails are sent from Outlook not from
OutlookExpress?